She joins Rand's group when the killer fog descends. She slaps him when he uses balefire telling him never to do that again. After he is wounded she leads the group back to Cairhien. She learns from Min what Elaida's embassy did to him. (ACoS,Ch36)
She is by Rand's bed when he wakes. She reluctantly leaves him to the Asha'man at his request. (ACoS,Ch41)
Cadsuane visits the Sun Palace with Daigian and Kumira. She quizzes Alanna about Rand but learns nothing new. She helps Sorilea with Alanna and in return Sorilea gives her advise on how to deal with Rand. Sorilea teaches her to Travel. They take a water oath to teach Rand laughter and tears, to teach him to be strong rather than hard. (TPoD,Ch12)
When Rand returns to the Sun Palace he sends for Cadsuane but she refuses to come. He goes to see her, tries unsuccessfully to intimidate her, then asks her to be his advisor. She sets a lot of conditions and Rand angrily starts to leave. She tells him that Callandor is flawed. (TPoD,Ch27)
ACoS,Glossary - Men she brings to the White Tower to tend to live markedly longer after being gentled than those brought by other sisters.
TPoD,Prologue - Verin questions the Aes Sedai prisoners three days after Cadsuane's arrival. Verin wonders what Cadsuane is doing.
TPoD,Ch12 - There are numerous mentions of the ornaments Cadsuane wears in her hair and how careful she is with them.
TPoD,Ch12 - Cadsuane considered bonding Rand herself or forcing Alanna to pass the bond to her, but Alanna's utter lack of control over Rand made her reconsider.